Niagara CAER Group Chemical Companies

National Emissions Reduction Masterplan
(NERM)

2005 Report for 2004 Emissions

Member Companies:

Chemtrade Logistics Inc.
CYTEC Canada Inc.
Durez Canada
Kemira Chemicals Canada Inc..
Lubrizol Canada Limited
Mancuso Chemicals Limited
Oxy Vinyls Canada Inc.
PolyOne Canada Inc.





Index

Page Description
1 Index
2 Company Contact List
3 Introduction
4 Summary
5 Explanations
6 Chart No. 1 - Chemical Emissions
7 Chart No. 2 - Production Volumes
8 Chart No. 3 - Chemical Emissions per 1000 Kg. Production
9 Chart No. 4 - Chemical Wastes
10 Chart No. 5 - Chemical Wastes per 1000 Kg. Production
11 Chart No. 6 - Combustion Emissions
12 Chart No. 7 - Combustion Emissions per 1000 Kg. Production
13 Table 1 - Chemical Emissions Greater than 1000 Kg. per year
14 Table 2 - Chemical Emissions less than 1000 Kg. per year
15 Table 3 - Chemical Emissions Per 1000 Kg. of Production, 1993 to 2004
16 Table 4 - Chemical Wastes
17 Table 5 - Chemical Wastes Per 1000 Kg. Of Production, 1993 to 2004
18 Table 6 - Combustion Emissions
19 Table 7 - Combustion Emissions per 1000 Kg. Production





Niagara CAER Group Chemical Companies

2005 Company Contact List

Company Name and Business Phone Number
Chemtrade Logistics Inc. Joe Iuliano 905.356.8763
CYTEC Canada Inc. Marc Macaulay
Ken Milo
905.374.5820
905.374.5812
Durez Canada Fort Erie Peter Collee
Robert Hunt
905.871.3206
905.871.3206
Kemira Chemicals Canada Inc..
St.Catharines
Bruno Montpetit
Clifton Brown
905.688.6470
905.688.6470
Lubrizol Canada Limited Blair Schiebel
Bill Goodfellow
905.358.5778
905.358.5778
Mancuso Chemicals Limited Gerry Hermelink 905.357.3626
Oxy Vinyls Canada Inc. Don Davidson
Mike Waher
905.374.5601
905.374.5646
PolyOne Canada Inc. Mario Tremblay 905.353.4229





Introduction

This report is issued by the Niagara CAER Group Chemical Companies as part of their commitment to being open to the public and to operating their businesses according to the principles of Responsible Care®, an initiative of The Canadian Chemical Producers’ Association. This is the thirteenth year of its publication. The results are presented as graphs with accompanying explanations for reported changes. Data is presented at the end of the report in the form of tables. Persons wishing to obtain more information are asked to e-mail their questions to pcollee@cogeco.ca, or they can contact the chemical company directly at the numbers listed in this report.

Operating the chemical plants with the absolute minimum impact on the health, safety and environmental well being of the communities in which we operate and live, continues to be our top priority. As may be seen from the graphs, we are making progress on our commitment.






Summary

In 2004 chemical emissions were 16.6% higher than they were in 2003 due to high production levels of some products that have higher levels of emissions associated with their manufacture; higher than normal surface water run-off containing nitrates and ammonia from one plant property and a 6.9% increase in overall production levels. Emissions will return to 2003 levels in 2005 and this coupled with a production increase of 7.1% will result in reducing emissions per thousand units of production by 56.6% compared with our base year of 1993 matching our best performance ever. Chemical wastes in 2004 increased by 3.2% due to the disposal of obsolete products. However, increased production resulted in wastes per thousand kilograms of production matching the lowest level ever achieved, 44.3% lower than our base year of 1993, and in 2005 we estimate we will improve on this record.

A very cold winter coupled with increased production led to a 3.2% increase in combustion emissions. However the increased production resulted in an all time low level of combustion emissions per thousand kilograms of production which will also be improved on in 2005.

 

 
Explanations

There were three contributing factors leading to a 16.6% increase in chemical emissions; an overall increase in production of 6.9%, an increase in production of some products that have higher chemical emissions associated with their manufacture, plus an increase in nitrate ion and ammonia emissions due to higher than normal rain water run-off from one plant property.  In 2005 it is expected that chemical emission rates will return to 2003 levels despite an increase in production levels of 7.9%. Chemical emissions per thousand kilograms of production increased by 7.1% in 2004 as the result of the overall emissions increase. For 2005 we are looking at this figure being reduced by 20% compared with 2004, matching the lowest levels ever achieved.

Chemical wastes increased by 3.2% in 2004 due to the disposal of inventories of obsolete products. This will continue in 2005 with the result that wastes will increase by another 4.7%. However, as Chart No. 5 shows, the increased production will off-set the increase in wastes resulting in the lowest level of wastes per thousand kilograms of production ever achieved in both 2004 (1.51 kg./1000 kg. production) and 2005 (1.46 kg./10000 kg. production). As may be seen by referring to Chart No. 5, there is a real trend towards leveling off of the data. Continued reductions in wastes per thousand units of production will present a challenge in the years to come. However, efforts will continue in this area in response to this challenge.

A 6.9% increase in production levels in 2004 combined with a very cold winter resulted in a 3.2% increase in combustion emissions. Most of the plant building heating is done with steam hence the effects of a cold winter on combustion emissions. Despite an estimated increase in production for 2005 of 7.9%, it is still estimated that combustion emissions in 2005 will be lower by 2.2% due to a variety of energy saving projects.

 






Chemical Emissions





Production Volume



































Chemical Emissions to Air and Water Greater than 1000 Kilograms (kg.) Per Year
Year 2004 Emissions and Comparisons with 2003 results

Table 1

Chem
No.
Plant
No.
Chemical Name Amount Released in 2004
Kilograms
Total
2004 kg.
Total
2003 kg.
% Change From 2003 Estimate 2005 kg.
Waterway Air
A4 4 Nitrogenous Material 2,952   2,952 2,858 +3.3 2,800
A5 1,4,5 Ammonia 4,352 35,378 39,730 34,655 +14.6 28,250
A6 4,5,7,9 Methanol   3,895 3,895 2,688 +44.9 2,861
A10 4 Iso Octane   4,495 4,495 5,951 -24.5 4,500
A13 4 Vinyl Chloride 1 1,333 1,334 1,033 +29.1 1,200
A17 9 Toluene   2,894 2,894 2,091 +38.4 2,100
A19 2,7,9 Kerosene Type Solvents   7,031 7,031 6,444 +9.1 7,930
A20 5 Ethyl Alcohol   59,514 59,514 50,807 +17.1 50,000
A21 1 Nitrate Ion 40,049   40,049 31,735 +26.2 40,000
                 
Emissions less than 1000 kg. per year - See Table 2 1,227 3,628 5,068 4,952 +2.3 5,023

Total Emissions

48,581

118,168

166,962

143,214

+16.6

144,664
Identification of Companies: (1) - Cytec;    (2) - Lubrizol;    (4) - Oxy Vinyls;    (5) - Durez;    (6) - Chemtrade Logistics;    (7) - Kemira Chemicals;    (8) - PolyOne;  (9) - Mancuso Chemicals   Number(3) - was CYRO, now shut down.
The numbering system has been maintained to allow comparison with previous years.







Chemical Emissions to Air and Water Less than 1000 Kilograms (kg.) Per Year
Year 2004 Emissosns and Comparisons with 2003 results

Table 2

Chem
No.
Plant
No.
Chemical Name Amount Released in 2004
Kilograms
Total
2004 kg.
Total
2003 kg.
% Change From 2003 Estimate 2005 kg.
Waterway Air
B4 7 Isopropanol   132 132 310 -57 310
B5 5,9 Phenol 5.4 730 735 710 +3.5 750
B7 5,9 Formaldehyde   192 192 183 +4.9 210
B9 1,9 Hydrochloric Acid   267 267 275 -2.9 300
B13 9 Xylene   761 761 1159 -34.3 1300
B18 6,9 Sulfur Dioxide   86 86 123 -30 80
B33 9 Ethyl Benzene   133 133 203 -34.5 220
B39 9 1,2,4-Trimethyl Benzene   139 139 125 +11.2 140
B42 9 Naphthalene   139 139 59 +135 59
B62 4 Oil and Grease ** 584   584 657 -11.1 500
B67 4 Phosphorus Salts 467   467 467 0 450
B77 4 Aluminum Ion 171   171 146 +17.1 150
B78 4 HCFC   748 748 13 10
B79 9 Methylene-bis-phenylisocyanate   160 160 180 -11.1 190
B80 9 Furfuryl Alcohol   141 141 122 +15.6 130
                 
9 Chemicals with emissions of 100 kg. or less ***     213 220 -3.2 224

Total Emissions in this category
1227 3628 5068 4952 +2.3 5023

Identification of Companies: (1) - Cytec;    (2) - Lubrizol;    (4) - Oxy Vinyls;    (5) - Durez;    (6) - Chemtrade Logistics;    (7) - Kemira Chemicals;    (8) - PolyOne;    (9) - Mancuso Chemicals;

** Tests show Oil and grease to be below Minimum Detection Levels, and probably they are zero. The amount reported is for the Minimum Detection Level.
*** Includes: Calcium Hydroxide, Ferric Oxide, Magnesium Oxide, Carbon Black, Zinc, Sulphuric Acid, Gasoline, Cyanide Ion, Diphenylamine.





Chemical Emissions per 1000 Kg. of Production, 1993 to 2004
Kg. of Emissions per 1000 Kg. of Production

Table 3

1993
Base Year *
1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005
(estimate)

Production Volume MM Kg

 

% Change from Base Year

232

 

 

 

264

 

 

+13.8

300.5

 

 

+29.5

308.6

 

 

+33

331.3

 

 

+42.8

342

 

 

+47.4

347

 

 

+49.6

335

 

 

+44.4

298.42

 

 

+28.6

346.3

 

 

+49.3

344.3

 



+48.4

368
(+6.9% vs 2003)

 


+58.6

397
(+7.9% vs 2004)

 


+71.1

Chemical Emissions MM Kg

 

% Change from Base Year

193,664

159,765

 

 

-18

150,272

 

 

-22

161,260

 

 

-17

149,078

 

 

-23

124,821

 

 

-36

135,879

 

 

-30

134,055

 

 

-31

140,296

 

 

-28

148,800

 


-24

143,214
Note 1

 


-26

166,962
(+16.6% vs 2003)

 


-13.8

144,664
(-13.4% vs 2004)

 


-25.3

Chemical Emissions per 1000 Units of Production
Kg. per 1000 Kg. of Production

 

% Change from Base Year

0.83

0.61

 

 

 

 

-27

0.50

 

 

 

 

-40

0.52

 

 

 

 

-37

0.45

 

 

 

 

-46

0.36

 

 

 

 

-57

0.39

 

 

 

 

-53

0.40

 

 

 

 

-52

0.47

 

 

 

 

-43

0.43

 

 

 

 

-48

0.42



 

 

-49.4

0.45
(+7.1% vs 2003)

 

 

 


-45.8

0.36
(-20% vs 2004)

 

 

 


-56.6


* Base Year - 1993 is the year against which plant performance is being compared. Hence 1993 in this report is called the "Base Year"

Note 1: Mancuso Chemical was added to the Niagara CAER Group in 2004. Their data is being reported for 2003 and 2004 with 2005 estimated.






Off-Site Chemical Waste Transfers - 2004 and Comparisons with 2003 Kg.

Table 4

Chem
No.
Plant
No.
Chemical Name Amount Released in 2004
Kilograms
Total
2004 kg.
Total
2003 kg.
% Change From 2003 Estimate 2005 kg.
Landfill Recycled/Treated
T1 1 Tributyl - Phosphine Sulfide 8,632   8,632 9,016 -4.3 9,000
T3 5 Phenol 40,742 11,700 52,442 26,905 +9.5 40,000
T4 1,2,4,7,8 Solvents; Waste & Lube Oils   228,080 228,080 261,414 -2.4 234,505
T8 2 Zinc   312 312 503 -3.8 500
T16 7 Surfactants   8,500 8,500 10,050 -19 10,000
T18 4 Vinyl Resins & Compounds 160,380   160,380 131,350 +22 200,000
T22 1,2 Phosphorous Salts   2,159 2,159 2,384 -9.4 1,955
T26 6 Sodium Chloride   580 580 1,362 -57.4 636
T27 7 Waste Corrosives - Obsolete Prod   24,700 24,700 1,910 +1193 10,000
T28 6 Neutralized Sulphuric Acid Sludge   0 0 34,260 -100 8,000
T29 2 Carbon, Activated       255 -100 50
T30 1 Hazardous Organic Wastes 260 59,853 60,113 56,913 +5.6 58,000
B7 5 Formaldehyde 871 7,450 8,321 395 +2006 7,400
B55.2 2 Sodium Hydroxide       200 -100  
                 
2 Chemicals with wastes of 100 kg. or less per year* 74   74 129 -40 124
Total Chemical Wastes
210,959 343,334 554,293 537,046 +3.2
580,170

Identification of Companies: (1) - Cytec;    (2) - Lubrizol;    (4) - Oxy Vinyls;    (5) - Durez;    (6) - Chemtrade Logistics;    (7) - Kemira Chemicals;    (8) - PolyOne;    (9) - Mancuso Chemicals

*Include: Antimony and Lead;









Chemical Wastes per 1000 Units of Production, 1993 to 2004
Kg. of Wastes per 1000 Kg. of Production

Table 5

1993
Base Year
1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005
(estimate)

Production Volume MM Kg

 

% Change from Base Year

232

 

 

 

264

 

 

+13.8

300.5

 

 

+29.5

308.6

 

 

+33

331.3

 

 

+42.8

342

 

 

+47.4

347

 

 

+49.6

335

 

 

+44.4

298.42

 

 

+28.6

346.3

 

 

+49.3

344.3

 



+48.4

368
(+6.9% vs 2003)


+58.6

397
(+7.9% vs 2004)


+71.1

Chemical Wastes Kg

 

% Change from Base Year

629,695

852,716

 

 

+35.4

1,136,384

 

 

+80.4

966,463

 

 

+53.5

754,389

 

 

+19.8

953,528

 

 

+51.4

745,804

 

 

18.4

724,589

 

 

+15.1

560,250

 

 

-11.1

570,391

 

 

-9.4

537,046


-14.7

554,293
(+3.2% vs 2003)

 

-12

580,170
(+4.7% vs 2004)





-7.9

Chemical Wastes per Production Unit Volume
Kg. per 1000 Kg. of Production

 

% Change from Base Year

2.71

3.23

 

 

 

 

+19.3

3.78

 

 

 

 

+39.5

3.13

 

 

 

 

+15.5

2.28

 

 

 

 

-15.9

2.76

 

 

 

 

+1.8

2.15

 

 

 

 

-21.0

2.16

 

 

 

 

-20.3

1.88

 

 

 

 

-30.6

1.65

 

 

 

 

-39.2

1.56



 

 

-42.4

1.51
(-3.2% vs 2003)

 

 

 


-44.3

1.46
(-3.3% vs 2004)

 

 

 


-46

 






Combustion Emissions
2004 Emissions and a comparison with 2003

Table 6

Combustion Product Component Amount Released
  2004 2003 2005 (Estimate)
Carbon Dioxide MM kg 54.62 52.96 53.43
Nitrogen Dioxide M kg 99.5 92.2 98.6
Carbon Monoxide M kg 38.9 36.9 38.4
Sulfur Oxides M kg 3.66 5.6 2.07
Methane M kg 1.78 0.96 1
Volatile Organic Carbon M kg 9.4 3.38 2.75
Totals Millions of kg 54.77
(+3.2% vs 2003)
53.1 53.57
(-2.2% vs 2004)









Combustion Emissions Per 1000 Kilograms of Production, 1993 to 2004

Table 7

1993
Base Year
1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005
(estimate)

Production Volumes Millions Kg

 

% Change from Base Year

232

 

 

Base Year

264

 

 

+13.8

300.48

 

 

+29.5

308.65

 

 

+33

331.2

 

 

+42.8

342

 

 

+47.4

347

 

 

+49.6

335

 

 

+44.4

298.4

 

 

+28.6

346.3

 

 

+49.3

344.3

 



+48.3

368
(+6.9% vs 2003)


+56.6

397
(+7.9% vs.
2004)

 

+71.1

Combustion Emissions Millions of Kg.

 

% Change from Base Year

56.29

 

 

Base Year

57.38

 

 

+1.9

60.4

 

 

+7.3

60.4

 

 

+7.3

59

 

 

+4.8

58.5

 

 

+3.9

60.9

 

 

+8.2

62.3

 

 

+10.7

55.75

 

 

-1.0

53.08

 

 

-5.7

53.1




-5.7

54.77




-2.7

53.57




-4.8

Combustion Emissions Kg. Per 1000 Kg. Of Production

 

% Change from Base Year

242.6

 

 

 

Base Year

217.3

 

 

 

-10.4

201

 

 

 

-17.1

195.7

 

 

 

-19.3

178.1

 

 

 

-26.6

172.2

 

 

 

-29

175.5

 

 

 

-27.7

186

 

 

 

-23.3

186.4

 

 

 

-23.0

153.3

 

 

 

-36.8

154.2

 

 


-36.4

148.8

 


-38.7

135

 



-44.4