| Niagara CAER Group Chemical Companies
National Emissions Reduction Masterplan
(NERM)
2005 Report for 2004 Emissions
Member Companies:
Chemtrade Logistics Inc.
CYTEC Canada Inc.
Durez Canada
Kemira Chemicals Canada Inc..
Lubrizol Canada Limited
Mancuso Chemicals Limited
Oxy Vinyls Canada Inc.
PolyOne Canada Inc. |
Niagara CAER Group Chemical Companies
2005 Company Contact List
|
| Company |
Name and Business |
Phone Number |
| Chemtrade Logistics Inc. |
Joe Iuliano |
905.356.8763 |
| CYTEC Canada Inc. |
Marc Macaulay
Ken Milo |
905.374.5820
905.374.5812 |
| Durez Canada Fort Erie |
Peter Collee
Robert Hunt |
905.871.3206
905.871.3206 |
Kemira Chemicals Canada Inc..
St.Catharines |
Bruno Montpetit
Clifton Brown |
905.688.6470
905.688.6470 |
| Lubrizol Canada Limited |
Blair Schiebel
Bill Goodfellow |
905.358.5778
905.358.5778 |
| Mancuso Chemicals Limited |
Gerry Hermelink |
905.357.3626 |
| Oxy Vinyls Canada Inc. |
Don Davidson
Mike Waher |
905.374.5601
905.374.5646 |
| PolyOne Canada Inc. |
Mario Tremblay |
905.353.4229 |
Introduction
|
This report is issued by the Niagara CAER Group Chemical Companies as part of their commitment to being open to the public and to operating their businesses according to the principles of Responsible Care®, an initiative of The Canadian Chemical Producers’ Association. This is the thirteenth year of its publication. The results are presented as graphs with accompanying explanations for reported changes. Data is presented at the end of the report in the form of tables. Persons wishing to obtain more information are asked to e-mail their questions to pcollee@cogeco.ca, or they can contact the chemical company directly at the numbers listed in this report.
Operating the chemical plants with the absolute minimum impact on the health, safety and environmental well being of the communities in which we operate and live, continues to be our top priority. As may be seen from the graphs, we are making progress on our commitment. |
| Summary |
In 2004 chemical emissions were 16.6% higher than they were in 2003 due to high production levels of some products that have higher levels of emissions associated with their manufacture; higher than normal surface water run-off containing nitrates and ammonia from one plant property and a 6.9% increase in overall production levels. Emissions will return to 2003 levels in 2005 and this coupled with a production increase of 7.1% will result in reducing emissions per thousand units of production by 56.6% compared with our base year of 1993 matching our best performance ever. Chemical wastes in 2004 increased by 3.2% due to the disposal of obsolete products. However, increased production resulted in wastes per thousand kilograms of production matching the lowest level ever achieved, 44.3% lower than our base year of 1993, and in 2005 we estimate we will improve on this record.
A very cold winter coupled with increased production led to a 3.2% increase in combustion emissions. However the increased production resulted in an all time low level of combustion emissions per thousand kilograms of production which will also be improved on in 2005.
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| Explanations |
There were three contributing factors leading to a 16.6% increase in chemical emissions; an overall increase in production of 6.9%, an increase in production of some products that have higher chemical emissions associated with their manufacture, plus an increase in nitrate ion and ammonia emissions due to higher than normal rain water run-off from one plant property. In 2005 it is expected that chemical emission rates will return to 2003 levels despite an increase in production levels of 7.9%. Chemical emissions per thousand kilograms of production increased by 7.1% in 2004 as the result of the overall emissions increase. For 2005 we are looking at this figure being reduced by 20% compared with 2004, matching the lowest levels ever achieved.
Chemical wastes increased by 3.2% in 2004 due to the disposal of inventories of obsolete products. This will continue in 2005 with the result that wastes will increase by another 4.7%. However, as Chart No. 5 shows, the increased production will off-set the increase in wastes resulting in the lowest level of wastes per thousand kilograms of production ever achieved in both 2004 (1.51 kg./1000 kg. production) and 2005 (1.46 kg./10000 kg. production). As may be seen by referring to Chart No. 5, there is a real trend towards leveling off of the data. Continued reductions in wastes per thousand units of production will present a challenge in the years to come. However, efforts will continue in this area in response to this challenge.
A 6.9% increase in production levels in 2004 combined with a very cold winter resulted in a 3.2% increase in combustion emissions. Most of the plant building heating is done with steam hence the effects of a cold winter on combustion emissions. Despite an estimated increase in production for 2005 of 7.9%, it is still estimated that combustion emissions in 2005 will be lower by 2.2% due to a variety of energy saving projects. |
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Chemical Emissions to Air and Water Greater than 1000 Kilograms (kg.) Per Year
Year 2004 Emissions and Comparisons with 2003 results
Table 1 |
Chem
No. |
Plant
No. |
Chemical Name |
Amount Released in 2004
Kilograms |
Total
2004 kg. |
Total
2003 kg. |
% Change From 2003 |
Estimate 2005 kg. |
| Waterway |
Air |
| A4 |
4 |
Nitrogenous Material |
2,952 |
|
2,952 |
2,858 |
+3.3 |
2,800 |
| A5 |
1,4,5 |
Ammonia |
4,352 |
35,378 |
39,730 |
34,655 |
+14.6 |
28,250 |
| A6 |
4,5,7,9 |
Methanol |
|
3,895 |
3,895 |
2,688 |
+44.9 |
2,861 |
| A10 |
4 |
Iso Octane |
|
4,495 |
4,495 |
5,951 |
-24.5 |
4,500 |
| A13 |
4 |
Vinyl Chloride |
1 |
1,333 |
1,334 |
1,033 |
+29.1 |
1,200 |
| A17 |
9 |
Toluene |
|
2,894 |
2,894 |
2,091 |
+38.4 |
2,100 |
| A19 |
2,7,9 |
Kerosene Type Solvents |
|
7,031 |
7,031 |
6,444 |
+9.1 |
7,930 |
| A20 |
5 |
Ethyl Alcohol |
|
59,514 |
59,514 |
50,807 |
+17.1 |
50,000 |
| A21 |
1 |
Nitrate Ion |
40,049 |
|
40,049 |
31,735 |
+26.2 |
40,000 |
| |
|
|
|
|
|
|
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| Emissions less than 1000 kg. per year - See Table 2 |
1,227 |
3,628 |
5,068 |
4,952 |
+2.3 |
5,023 |
Total Emissions |
48,581 |
118,168 |
166,962 |
143,214 |
+16.6 |
144,664 |
| Identification of Companies: (1) - Cytec; (2) - Lubrizol; (4) - Oxy Vinyls; (5) - Durez; (6) - Chemtrade Logistics; (7) - Kemira Chemicals; (8) - PolyOne; (9) - Mancuso Chemicals Number(3) - was CYRO, now shut down. |
| The numbering system has been maintained to allow comparison with previous years. |
Chemical Emissions to Air and Water Less than 1000 Kilograms (kg.) Per Year
Year 2004 Emissosns and Comparisons with 2003 results
Table 2 |
Chem
No. |
Plant
No. |
Chemical Name |
Amount Released in 2004
Kilograms |
Total
2004 kg. |
Total
2003 kg. |
% Change From 2003 |
Estimate 2005 kg. |
| Waterway |
Air |
| B4 |
7 |
Isopropanol |
|
132 |
132 |
310 |
-57 |
310 |
| B5 |
5,9 |
Phenol |
5.4 |
730 |
735 |
710 |
+3.5 |
750 |
| B7 |
5,9 |
Formaldehyde |
|
192 |
192 |
183 |
+4.9 |
210 |
| B9 |
1,9 |
Hydrochloric Acid |
|
267 |
267 |
275 |
-2.9 |
300 |
| B13 |
9 |
Xylene |
|
761 |
761 |
1159 |
-34.3 |
1300 |
| B18 |
6,9 |
Sulfur Dioxide |
|
86 |
86 |
123 |
-30 |
80 |
| B33 |
9 |
Ethyl Benzene |
|
133 |
133 |
203 |
-34.5 |
220 |
| B39 |
9 |
1,2,4-Trimethyl Benzene |
|
139 |
139 |
125 |
+11.2 |
140 |
| B42 |
9 |
Naphthalene |
|
139 |
139 |
59 |
+135 |
59 |
| B62 |
4 |
Oil and Grease ** |
584 |
|
584 |
657 |
-11.1 |
500 |
| B67 |
4 |
Phosphorus Salts |
467 |
|
467 |
467 |
0 |
450 |
| B77 |
4 |
Aluminum Ion |
171 |
|
171 |
146 |
+17.1 |
150 |
| B78 |
4 |
HCFC |
|
748 |
748 |
13 |
∞ |
10 |
| B79 |
9 |
Methylene-bis-phenylisocyanate |
|
160 |
160 |
180 |
-11.1 |
190 |
| B80 |
9 |
Furfuryl Alcohol |
|
141 |
141 |
122 |
+15.6 |
130 |
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| 9 Chemicals with emissions of 100 kg. or less *** |
|
|
213 |
220 |
-3.2 |
224 |
Total Emissions in this category |
1227 |
3628 |
5068 |
4952 |
+2.3 |
5023 |
Identification of Companies: (1) - Cytec; (2) - Lubrizol; (4) - Oxy Vinyls; (5) - Durez; (6) - Chemtrade Logistics; (7) - Kemira Chemicals; (8) - PolyOne; (9) - Mancuso Chemicals;
** Tests show Oil and grease to be below Minimum Detection Levels, and probably they are zero. The amount reported is for the Minimum Detection Level.
*** Includes: Calcium Hydroxide, Ferric Oxide, Magnesium Oxide, Carbon Black, Zinc, Sulphuric Acid, Gasoline, Cyanide Ion, Diphenylamine.
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Chemical Emissions per 1000 Kg. of Production, 1993 to 2004
Kg. of Emissions per 1000 Kg. of Production
Table 3 |
|
1993
Base Year * |
1994 |
1995 |
1996 |
1997 |
1998 |
1999 |
2000 |
2001 |
2002 |
2003 |
2004
|
2005
(estimate) |
Production Volume MM Kg
% Change from Base Year |
232
|
264
+13.8 |
300.5
+29.5 |
308.6
+33 |
331.3
+42.8 |
342
+47.4 |
347
+49.6 |
335
+44.4 |
298.42
+28.6 |
346.3
+49.3 |
344.3
+48.4 |
368
(+6.9% vs 2003)
+58.6
|
397
(+7.9% vs 2004)
+71.1
|
Chemical Emissions MM Kg
% Change from Base Year |
193,664 |
159,765
-18 |
150,272
-22 |
161,260
-17 |
149,078
-23 |
124,821
-36 |
135,879
-30 |
134,055
-31 |
140,296
-28 |
148,800
-24
|
143,214
Note 1
-26
|
166,962
(+16.6% vs 2003)
-13.8
|
144,664
(-13.4% vs 2004)
-25.3
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Chemical Emissions per 1000 Units of Production
Kg. per 1000 Kg. of Production
% Change from Base Year |
0.83 |
0.61
-27 |
0.50
-40 |
0.52
-37 |
0.45
-46 |
0.36
-57 |
0.39
-53 |
0.40
-52 |
0.47
-43 |
0.43
-48 |
0.42
-49.4 |
0.45
(+7.1% vs 2003)
-45.8
|
0.36
(-20% vs 2004)
-56.6
|
* Base Year - 1993 is the year against which plant performance is being compared. Hence 1993 in this report is called the "Base Year"
Note 1: Mancuso Chemical was added to the Niagara CAER Group in 2004. Their data is being reported for 2003 and 2004 with 2005 estimated.
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Off-Site Chemical Waste Transfers - 2004 and Comparisons with 2003 Kg.
Table 4 |
Chem
No. |
Plant
No. |
Chemical Name |
Amount Released in 2004
Kilograms |
Total
2004 kg. |
Total
2003 kg. |
% Change From 2003 |
Estimate 2005 kg. |
| Landfill |
Recycled/Treated |
| T1 |
1 |
Tributyl - Phosphine Sulfide |
8,632 |
|
8,632 |
9,016 |
-4.3 |
9,000 |
| T3 |
5 |
Phenol |
40,742 |
11,700 |
52,442 |
26,905 |
+9.5 |
40,000 |
| T4 |
1,2,4,7,8 |
Solvents; Waste & Lube Oils |
|
228,080 |
228,080 |
261,414 |
-2.4 |
234,505 |
| T8 |
2 |
Zinc |
|
312 |
312 |
503 |
-3.8 |
500 |
| T16 |
7 |
Surfactants |
|
8,500 |
8,500 |
10,050 |
-19 |
10,000 |
| T18 |
4 |
Vinyl Resins & Compounds |
160,380 |
|
160,380 |
131,350 |
+22 |
200,000 |
| T22 |
1,2 |
Phosphorous Salts |
|
2,159 |
2,159 |
2,384 |
-9.4 |
1,955 |
| T26 |
6 |
Sodium Chloride |
|
580 |
580 |
1,362 |
-57.4 |
636 |
| T27 |
7 |
Waste Corrosives - Obsolete Prod |
|
24,700 |
24,700 |
1,910 |
+1193 |
10,000 |
| T28 |
6 |
Neutralized Sulphuric Acid Sludge |
|
0 |
0 |
34,260 |
-100 |
8,000 |
| T29 |
2 |
Carbon, Activated |
|
|
|
255 |
-100 |
50 |
| T30 |
1 |
Hazardous Organic Wastes |
260 |
59,853 |
60,113 |
56,913 |
+5.6 |
58,000 |
| B7 |
5 |
Formaldehyde |
871 |
7,450 |
8,321 |
395 |
+2006 |
7,400 |
| B55.2 |
2 |
Sodium Hydroxide |
|
|
|
200 |
-100 |
|
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|
|
|
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|
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| 2 Chemicals with wastes of 100 kg. or less per year* |
74 |
|
74 |
129 |
-40 |
124 |
Total Chemical Wastes |
210,959 |
343,334 |
554,293 |
537,046 |
+3.2 |
580,170
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Identification of Companies: (1) - Cytec; (2) - Lubrizol; (4) - Oxy Vinyls; (5) - Durez; (6) - Chemtrade Logistics; (7) - Kemira Chemicals; (8) - PolyOne; (9) - Mancuso Chemicals
*Include: Antimony and Lead; |
Chemical Wastes per 1000 Units of Production, 1993 to 2004
Kg. of Wastes per 1000 Kg. of Production
Table 5 |
|
1993
Base Year |
1994 |
1995 |
1996 |
1997 |
1998 |
1999 |
2000 |
2001 |
2002 |
2003 |
2004
|
2005
(estimate) |
Production Volume MM Kg
% Change from Base Year |
232
|
264
+13.8 |
300.5
+29.5 |
308.6
+33 |
331.3
+42.8 |
342
+47.4 |
347
+49.6 |
335
+44.4 |
298.42
+28.6 |
346.3
+49.3 |
344.3
+48.4
|
368
(+6.9% vs 2003)
+58.6 |
397
(+7.9% vs 2004)
+71.1 |
Chemical Wastes Kg
% Change from Base Year |
629,695 |
852,716
+35.4 |
1,136,384
+80.4 |
966,463
+53.5 |
754,389
+19.8 |
953,528
+51.4 |
745,804
18.4 |
724,589
+15.1 |
560,250
-11.1 |
570,391
-9.4 |
537,046
-14.7 |
554,293
(+3.2% vs 2003)
-12 |
580,170
(+4.7% vs 2004)
-7.9 |
Chemical Wastes per Production Unit Volume
Kg. per 1000 Kg. of Production
% Change from Base Year |
2.71 |
3.23
+19.3 |
3.78
+39.5 |
3.13
+15.5 |
2.28
-15.9 |
2.76
+1.8 |
2.15
-21.0 |
2.16
-20.3 |
1.88
-30.6 |
1.65
-39.2 |
1.56
-42.4 |
1.51
(-3.2% vs 2003)
-44.3
|
1.46
(-3.3% vs 2004)
-46
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Combustion Emissions
2004 Emissions and a comparison with 2003
Table 6 |
| Combustion Product Component |
Amount Released |
| |
2004 |
2003 |
2005 (Estimate) |
| Carbon Dioxide MM kg |
54.62 |
52.96 |
53.43 |
| Nitrogen Dioxide M kg |
99.5 |
92.2 |
98.6 |
| Carbon Monoxide M kg |
38.9 |
36.9 |
38.4 |
| Sulfur Oxides M kg |
3.66 |
5.6 |
2.07 |
| Methane M kg |
1.78 |
0.96 |
1 |
| Volatile Organic Carbon M kg |
9.4 |
3.38 |
2.75 |
| Totals Millions of kg |
54.77
(+3.2% vs 2003) |
53.1 |
53.57
(-2.2% vs 2004) |
Combustion Emissions Per 1000 Kilograms of Production, 1993 to 2004
Table 7 |
|
1993
Base Year |
1994 |
1995 |
1996 |
1997 |
1998 |
1999 |
2000 |
2001 |
2002 |
2003 |
2004
|
2005
(estimate) |
Production Volumes Millions Kg
% Change from Base Year |
232
Base Year |
264
+13.8 |
300.48
+29.5 |
308.65
+33 |
331.2
+42.8 |
342
+47.4 |
347
+49.6 |
335
+44.4 |
298.4
+28.6 |
346.3
+49.3 |
344.3
+48.3
|
368
(+6.9% vs 2003)
+56.6 |
397
(+7.9% vs.
2004)
+71.1 |
Combustion Emissions Millions of Kg.
% Change from Base Year |
56.29
Base Year |
57.38
+1.9 |
60.4
+7.3 |
60.4
+7.3 |
59
+4.8 |
58.5
+3.9 |
60.9
+8.2 |
62.3
+10.7 |
55.75
-1.0 |
53.08
-5.7 |
53.1
-5.7 |
54.77
-2.7 |
53.57
-4.8
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Combustion Emissions Kg. Per 1000 Kg. Of Production
% Change from Base Year |
242.6
Base Year |
217.3
-10.4 |
201
-17.1 |
195.7
-19.3 |
178.1
-26.6 |
172.2
-29 |
175.5
-27.7 |
186
-23.3 |
186.4
-23.0 |
153.3
-36.8 |
154.2
-36.4 |
148.8
-38.7 |
135
-44.4 |
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